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產(chǎn)品基本信息
產(chǎn)品編號：D469595
產(chǎn)品名稱：(αR)-α-[[(1,1-Dimethylethoxy)carbonyl]amino]-benzeneacetic Acid
產(chǎn)品CAS：33125-05-2
規(guī)格含量：2.5g
產(chǎn)品價(jià)格：面議
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產(chǎn)品詳細(xì)介紹
標(biāo)準(zhǔn)品編號:
D469595
名稱:
(αR)-α-[[(1,1-Dimethylethoxy)carbonyl]amino]-benzeneacetic Acid
別名:
(R)-α-[[(1,1-Dimethylethoxy)carbonyl]amino]-benzeneacetic acid; D-N-Carboxy-2-phenyl-glycine N-tert-butyl Ester; (2R)-2-(tert-Butoxycarbonylamino)-2-phenylethanoic Acid; (R)-2-((tert-Butoxycarbonyl)amino)-2-phenylacetic Acid; (R)-2-tert-Butoxycarbonylamino-2-phenylethanoic Acid; (R)-N-(tert-Butyloxycarbonyl)phenylglycine; (R)-N-Boc-2-amino-2-phenylacetic Acid; (R)-N-Boc-2-phenylglycine; (R)-[(tert-Butoxycarbonyl)amino]phenylethanoic Acid; BOC-D-Phg-OH; D-(-)-N-(tert-Butoxycarbonyl)phenylglycine; D-2-tert-Butoxycarboxamido-2-phenylacetic Acid; D-N-(tert-Butoxycarbonyl)-2-phenylglycine; N-(tert-Butoxycarbonyl)-D-2-phenylglycine; N-(tert-Butoxycarbonyl)-D-α-phenylglycine; N-(tert-Butoxycarbonyl)phenylglycine; N-Boc-D-phenylglycine; N-tert-Butoxycarbonyl-D-phenylglycine; N-tert-Butyloxycarbo
CAS號:
33125-05-2
分子式:
C??H??NO?
外觀:
白色固體
熔點(diǎn):
91-93°C
分子量:
251.28
儲存:
冰箱保存
溶解性:
DMSO, Methanol
種類:
Building Blocks; Catalyst;
應(yīng)用:
(αR)-α-[[(1,1-Dimethylethoxy)carbonyl]amino]-benzeneacetic Acid is D-(+)-2-Phenylglycine (P327125) with Boc protecting group. (αR)-α-[[(1,1-Dimethylethoxy)carbonyl]amino]-benzeneacetic Acid is used as part of a catalyst combination to catalyze regioselective [4 + 2] cycloadditions of β-substituted cyclic enones and polyconjugated malononitriles. It can also be used to catalyze stereoselective preparation of polyfunctional nitrocyclohexene carboxaldehydes.
參考文獻(xiàn)
Feng, X., et al.: J. Amer. Chem. Soc., 134, 19942 (2012); Jia, Y., et al.: Tetrahedron Asym., 22, 2018 (2011)
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